George wasn't always Hollywood's hottest bachelor. Back in 1989, he was a married man! The rising star and actress Talia Balsam tied the knot in a quickie Vegas ceremony just months after George ended his two-year romance with Kelly Preston. George and Talia divorced after three years. "I probably -- definitely -- wasn't someone who should have been married at that point," he later told Vanity Fair. George went on to woo an onslaught of model types; Talia, meanwhile, has been married to "Mad Men" star John Slattery since 1998.