Who: Talia Balsam
What: Married from 1989 to 1993
Of all the women on this list, Balsam is the only one to have taken Clooney to the altar. You may notice that's not Clooney in the photo, however. It's John Slattery, Balsam's current, real-life husband and, on "Mad Men," her on-screen ex-husband.
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