Khloe Kardashian: Kris Humphries 'Rubbed Me the Wrong Way'

What a charmer.

Kris Humphries never stood a chance with his in-laws -- particularly Khloe Kardashian, Kim's 27-year-old sister.

Rehashing Kim and Humphries' ill-fated, 72-day marriage to Jay Leno on "The Tonight Show" Tuesday, Khloe recalled how the NBA star, 26, made a very bad first impression.

PHOTOS: Sigh! Kim and Kris' wedding album

"When I met Kris the very first time, I had just landed in New York and it was late at night ... and he was in Kourtney and Kim's suite," recalled Khoe, who is still very happily married to Dallas Mavericks player Lamar Odom after two years.

"And I went in there to say, 'Hi' because Kim was like, 'Oh, I wanna introduce you to my friend,'" she recalled. "They'd just started dating." (After splitting from Reggie Bush in spring 2010, Kardashian dated NFL star Miles Austin and model Gabriel Aubry before stepping out with Humphries in December 2010.)

VIDEO: Kris grabs Kim's booty in the pool on their sexy honeymoon

Meeting outspoken Khloe, Humphries immediately pulled a faux pas, she recalled. "And you know, one of the first things that came out of his mouth -- like within the first five minutes -- was, 'So, how much you getting paid to fake your marriage? Like, how long are you gonna keep this up for?'"

Khloe wasn't amused. "I was like, 'Dude, I don't know if you're trying to make me laugh ... [He] just rubbed me the wrong way."

PHOTOS: Kim's lousy, lousy year

"So, ever since then, I had a very defensive wall brought up."

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